Alright, here you go:
> tar cpf mypdfs.tar *.pdf
That works, if you know where the files are... If you first have to find them, use the following:
> find / -name "*.pdf" -exec tar rpf mypdfs.tar {} ";"
Pay attention:
1. Change the '/' to the folder your searching in.
2. You need all the quotes, don't forget them.