Do you have a copy of TextWrangler? If not you can download it--it is free from Bare Bones.
http://www.barebones.com/products/textwrangler/
I had determinedly tried to wreck a file, which was very small, and contained a minimal amount of formatting information (basically, just a particular font). It persisted in being opened correctly in Word and TextEdit. I opened it in TextWrangler, which would open it and display the sort of thing you would see in a hex editor, that is every thing encoded in the file, but in a more readily readable form. Here's what it looks like:
{\rtf1\ansi\ansicpg1252\cocoartf949\cocoasubrtf350
{\fonttbl\f0\froman\fcharset0 TimesNewRomanPSMT;}
{\colortbl;\red255\green255\blue255;}
\vieww9000\viewh9600\viewkind0
\deftab709
\pard\pardeftab709\ql\qnatural\pardirnatural
\f0\fs24 \cf0 This was a Neo office document. I'm trying to mess it up.\
}
You can see that it was originally in rtf form, with TimesNewRoman as the font. The actual text is the simple statement: This was a Neo office document. I'm trying to mess it up.
You might try downloading TextWrangler, then drop one of the smaller files on to it and see what you get.