Windows is a pain.
PDF integration to browsers suck. When you open a PDF in FF, you need to move the mouse around, can't use any shortcuts for find, next tab, move, close, etc... and searching on a PDF of 4 pages takes as long as searching in a whole bible in OS X PDFs.
Dialogues are retarded. "Dismiss" a meeting in Outlook? No thanks, I want to IGNORE it, not dismiss. Are you sure you want to cancel? Yes, I hit cancel...
F9 and F10 keys as in Mac OS X, I need those. The alt tab gets annoying, I still need to hit 20 keys to move when I move to a certain window or to go thru the taskbar. When I hit an item on taskbar if it has multiple windows, the behavior is retarded again...
Plus all programs are in a slow to access start bar, smb default connection security was maybe good for 1940s standards, all services are in odd locations and most details seem very poorly thought. Including shortcuts. Hitting ctrl-something instead of cmd-something feels on the wrists after a full work day.
Search in Windows is ... poor.
It's not really exceptional multitasking if you have too many things sucking on resources in system tray, task bar that isn't functional (when I click on an application, I want ALL its windows open), with the copy and paste annoyances... it's like trying to work in an office when something interrupts you every 30 seconds. And you can't close the door and unplug the phone. I just don't ever feel using Windows can get anyone do productive work, unless they are connected to their server and use PuTTy all day to get their job done via ssh on a console. Multitabbing.
I'm so happy that Windows is enough as a virtual machine at work if you want to use anything else...

Or could run Windows and get 60 % of the job done in whatever OS in Workstation.