Replacing The Slot-Loading Cd-Drive

yes you can. there are excellent guides on iFixIt:

For CoreDuo MacBooks: http://www.ifixit.com/Guide/Mac/MacBook-Core-Duo/86
For Core2Duo MacBooks: http://www.ifixit.com/Guide/Mac/MacBook-Core-2-Duo/Optical-Drive-Replacement/116/9/

Other guides: http://www.ifixit.com/Guide/Mac/

it looks like it's a little complicated, though not too bad. Certainly a lot easier than an iBook (then again, brain surgery was easier than replacing drives in an iBook!). If you are game, my advice is to go slow and keep a careful log as to which part screws in where, and in what order.
 
As long as you have taken apart some laptops and feel comfortable doing it, have the correct manual and tools, patience and some good system for the screws and parts why not.
An ice cube tray or two works great for storage for the screws during the upgrade.
 
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