You will need to provide a lot more information, such as:
What service file? Be specific with the name of the file, and its location on your hard drive. You may find that you don't really need to change permissions. You don't need to do that from the terminal, usually, but through the info window for the file itself. A file that is used within the system, may not let you do that anyway, and you could end up ruining your system, and needing to erase and install.
Someone will be more familiar that I am about some of the system files, but you need to identify which file you are asking about.
Also, what is your higher goal here? What do you want to achieve?